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Átírás

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6 cjj KATAJ1H3 B npombwj1ehhocth N C "zs Mr Sn Crw r/n Ha BXOllC Ha BblXOl1e J10" J 'J HS HS A"' r pv"tj"v nobbchj1h B CpeJtHeM Jto 21 r Sn [ ttto HHK3K He CKaJaJlOCb H3 3<j><j>eKTHBHOCTH pe3kt/cyr YJtaJeHHS 1 : ~'! ' cynb<j>hlt3 OHa nonpe)j(hemy 6blJa 6JH3KOH K 100 % (CM phc 5 H Ta6J 2) pa60tb1 JtOCTHrna 100 % (phc 5) ljepe3 11 JtHeH Ha '800 CJelJYlOmHe 3 Mec H3~1laJH cta6hjbhoctb pa60 j 1 ~ 06 Tbl peaktop3 nph CpelJHe HarpY3Ke 26 r S/J pe 1[; 6 3KT/cyr (rn6n 2); nph 3TOM <j>3kthtfeckh OH3 KOJe /' aJ13Cb B UJHpOKHX npejtejax (OT 10 Jto 33 r Sn pel 4 ): 3KT/cyr) BHJtHO (CM phc 5 H Ta6n 2) ttto peaktop : 200 a 02 HMeJl BblCOKYO YCTOHtfHBOCTb K YKaJ3HHbM BblUJe t : 0 <j>jlykty3qhslm cpejthrs 3<j><j>eKTHBHOCTb YJtaJeHHS BpeMJ CYT CYJb<pHQa COCTaBJJlJa 94 % OQHaKo nph HarpY3Kax ~fv' 0' H S/( ) npebbluj31omhx 33 r Sn peakt/cyr Ha6JOlJaJlOCb J't"t"KTHBHOCTb 0 arpy3ka r ncyr BocnpOH3BOlJHMOe na!!ehhe 3<j><j>eKTHBHOCTH YlJaJle + 3<1Kf1eCTHBHOCTL 6 HarpyJKa HHJ CYJb<j>HlJa (BnJOTb Jto 81 %) 4TO n03bojret CtfH T3Tb 3TO 3H3tfeHHe H3rpY3KH npejtenbhblm J1J1J1 HC " 6 nojb3yemoh peaktophoh KOHCTpYKQHH C nojtatfeh KHC l' C~sMrS/n CfeJr/n H2S a BXOle 0 H2S /la BblXOJle 6 DeJ10K a ~O j! 0 O' "l' BpeMJ CYT Pac U 6blXoOe 4 3a6ucUMocmu peokmopo KOHleHmpaquu KoHleHmpalluu 6e1lKO cyj1bcpuoa (0) HOZpy3KU HO 6xoOe ''~ 1 4 no cyj1bcpuoy U 3rfxPeKmu6Hocmu yoanehwl CYJ1bf/Juoo (6) 400 : 6 me'lehue nep6oz0 lu1cjla pa60mbl peakmopa om 6peMeHU 0 ' ~ OrP ~ 0 0 \ peaktopa He npebblwajh 10 % OT KOHQeHTpaLlHH BpeMS cyt CYJb<pHJta Ha BxoJte MO)J(HO 33KJlOtfHTb ttto nocjejt HHH YJtaJJlJCS npehmymectbehho no peakllhh (1) 3<!x1>eKTHBHOCTb % Harpy3Ka r S(ncyr) CJeJtYeT JaMeTHTb 'fro B 3TOH cephh onbltob nojtatfa 31jJljleKTBHOcrb 6larpyJCa 6 : [ Cy6CTpaTa ocywectbjslj3cb COBMeCTHO C MHHepanb 100 ~ ~ " 30 HOH CpeJtOH Te OJtHHM HaCOCOM # ' # ~ " t v v t' ' 113 phc 4 6 BHJtHO 'fro HMeJH MeCTO 3HatfHTeJb Hble <pjyktyallhh HarpY3KH peaktopa no CYJb<pHJtY ~ 66 f!+6 666%1:16 v 6 66 "6 4TO BepOJTHO CBJl3aHO C XHMH4eCKOH Ja HJbHOC 60 6 ~ ~ U"' 6 TblO cy6ctpata B CBJl3H C 3T1M ljjj nocjeqyo~hx ~ ~ 6 6 &:t KcnepHMeHTOB B annaparyphyo cxemy 6blJH BHece Hbl CJeJtYOwHe H3MeHeHHJ: Cy6CTp3T H MHHepaJbHaJ ~6 " 10 6 l cpejta nojtabajlhcb pajhblm KaHaJlaM H KoHueHTpH pobahhblh pactbop cy6ctpata cojtep)kajjcr nojt apro ' HOM J1J1J1 npejtotbpamehhj ero XHMHtfeCKOrO OKHC 0 0! JeHHJ BpeMScyr BTOpOH LloJKJJ HcnblTaHoJH peaktopa HaYaJH co Puc 5 3a6UC/L\lOCmu KoHleHmpal/UU cyjlbrpuoa Ha 6Xooe 11! cpejtheh HarpY3KH 11 r Sn peakt /cyr H BpeMeHH U 6blxooe peakmopo KOHleHmpallUU 6e1lKO (a) Ha?PY3KU r!! npe6blbahhj )J(H!XKOCTH B peaktope 06 cyr 3<p no cyj1bcpuoy U 3CPCPeKmu6Hocmu yoanehwl CYJ1bf/Juoo (6) <pekthbhoctb YJtaJeHHJ CYJb<j>HJta ~e Ha 3" JteHb 6 me"ehue 6mopozo lu1cjla pa60mbl peakmopa om 6peMeHU : 52 '; " \ j! ~! "C:::;;'~ 2 0

7 :: 6HOKATAnH3 ~ :;:f;;~f " Ta6n H ua 31j>j>eKTHBHOCTb pa60tbl peaktopa B TeqeHHe nepboro ~HKJla 3KCnepHMeHTOB n HarpY3ka no cynbc}lhlty 3cj1cj1CkTHBHOCTL po nonjkhtenlhoctl cyr Bn rvt cynlcjlhlta % r S/(n cyr) " Yl1aJ1eHHR % % % % % %00 Ta6nHua 2 31j>j>eKTHBHOCTb pa6otbl peaktopa B TeqeHHe BToporo UHKJla 3KcnepHMeHToB Harp}'3ka COOTHoweHHe Bn 3cj1cj1ekTHBHOCTh npol10'1jkh TenHOCTL cyr no CynL"'Hl1Y 't' ' Cyr Yl1aJ1eHHH cynlcjlhlla % PH notokob r S/(Jl"C)'T) cpella/cyjlb~)hll 108% % %00 68%02 128*53 ]4 211% %008 ]000%00 70%02 134%] * * % % * 27 Ta6nHua 3 31j>j>eKTHBHOCTb pa6otbl peaktopa B TeqeHHe TpeTbero UHKJla 3KcnepHMeHToB KOHueHTpaUHR CTeneH npollonjkh Harp}'3Ka 3cj1cj1ekTHBHOCT COOTHoweHHe cynbc}lata KoHBepcHH TeJlHOCTL no cyjltcjlhlty Bn cyr Yl1aJ1eHHR phawx notokob Ha BLXOl1e cynlcjlhlta cyr r S/(nocyr) cynlcjllula % cpella/cyjllcjllul Mr Sn B cynlcjla:r % 47 ]13% % % ]0 70%04 61 % ]0 407%274 80*59 52 ]43* % %24 73*04 61%14 562%448 97% * * %160 79*09 67*17 162*159 37:1:01 Jlopona TOJlbKO B rajobyo <l>a3y 3ro nobhzlhmomy (phc 6) a peaktop ncmohctphpobaj noqth 100 % CBH3aHO C HeXBaTKOH KHCJlOpona B )KHZlKOH <l>aje H3 HYO 3<l><l>eKTHBHOCTb ynajehhh cynb<l>hzla (Ta6n 3) 3a nhmhtal1hh era MacconepeHoca qepe3 rpahhuy nocnejjyqluee YBenHtJeHHe HarpY3KH no 15 r S n pajnena <l>aj peakt /cyr npakthtjeckh He CKaJaJlOCb Ha 3<l><l>eKTHB Ha cnej:jyloluem nane 3KcnepHMeHTOB an napa HOCTH ynajehhh cynb<l>hna aha OCl1HJJHpOBaJla ryphoe o<l>opmjehhe 6blJH BHeceHbl HOBbe 113MeHe OKOJO 98 % (CM Ta6J 3) H1~ nona'a K1CJOpona ocyll1ectbj~jacb Henocpen OOCJenH11 Mec~~ 1CCJenoBaH11 6blJ nocbhmeh CTBeHHO B )KHnKYO <l>a3y HatJaJlbHaH HarpY3Ka no onpenejehho MaKCHMaJlbHO BO3MO)KHOH HarpY3KH CYJb<l>Hny COCTaBJHJa 11 r S/J peakt /cyr a BpeMH ZlJ]HnaHHoH KOHCTPYKl1HH nph ee 3HatJeHHH 24 r S/J npe6bbahhh )KHZlKOCTH B peaktope 05 cyr (Ta6J 3) peakt /cyr 3<l><l>CKTHBHOCTh ynajehhj cyjb<l>hzla CJer B retjehhc 2 Mec HcnblTaHHH KOHl1eHTpal1HH 6Ho Ka CHH3HJ1aCb no 96 % Hano OTMCTHTb tjto nph MaCCbl B peaktope YBeJHtJl1JaCb nollth B 100 pa3 Bcex Tpex BbllllcYKa3aHHblx HarpY3Kax TOJbKO He3Ha 53

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9 '" ~" J' Cc _lata: K HCTOPHH OTEqECTBEHHOro K! Jlr1TEPATYPA ton of hydrogensulphde: PhD thess Wagenngen Agrculture Unversty Netherlands 1996 TexHoJtorwr nepepa60tkh cephhctoro nphpollhoro 7 Henshaw PF Zhu W Water Res 2001 Vol 35 ra3a: CnpaBO4H1K nol pell AH A~)aHaCbeBa M: N2 15 P 3605 Hellpa KQlO7CHblU CB llahun06u'l/la 8 Chung r:c Huang C Lu CH Ba H J Ar Waste HO:JCeaHUK06a AH Manag Assoc 2001 Vol 51 N'!! 2 P 163 AHa3po6Hal 6HOJOrH'eCKaJ O'lHCTKa CTO'{HbX BOll 9 Sublette KL Kolhatkar R Raterman K Bodegrada (HTOm HaYXH H TeXHHKH Cep EHOTeXHoJtomll) M: ton 1998 Vol 9N'!! 34 P 259 BHHHTH 1991 T 29 10Janssen AJ Rutenberg R Busman C!: Water Sc 3 Envronmental Technologes to treat sulphur polluton Technol 2001 Vol 44N'!! 8 P 85 Eds P Lens PL Hulshoff London: WA Publshng Ka'lO:J/C/bU CB (/Jeoopoou'l BB 3KoJtorH H npom:: 2000 CTb POCC N2 2 C 33 4 Busman C ndustra! applcatons of new sulphur technolo 12Janssen Albert!:H Ma SC Lens P Lettnga G gy Proc of TMR Summer School «The Bologcal sul Botechnol and Boeng 1997 Vol 53 P 32 phur cycle»: Envron Sc and Technol (Wagenngen 13 Trper HG Schlegel HG J Mcrobol and Serol ; Netherlands 1924 Aprl 1999) Wagenngen Vol 30 P 225 : 5 Busman C Botechnologcal sulphde removal wth 14J1ypbe /0/0 AHaJlHTH'eCKaJ XHMHR npomblulj1ehhblx 1 oxygen: PhD thess Wagenngen Agrculture Unver CTO'HbX BOll M: XHMH 1984 sty Netherlands llocoH P 3'lJ/uom ll 31V1uom ~"ll:jcohc K CnpaBO'l 6 Janssen AlbertJH Formaton and collodal behavor of HHK 6HoxHMHKa M: MHP 1991 elemental sulphur produced from the bologcal oxda 16llne2eJ/b r 06llall MHKp06HoJtorH)J M: MHP 1987 " j PA3BMTME OprAHM'ECKOrO KATAnM3A B MHCTMTYTE OprAHMLlECKOM XMMMM MM HA 3EnMHCKOrO PAH (K 70flETHO co AHH MA PJlWeH~eBa r1hctl1tyt OpraHl1YeCKO~ Xl1 Ml M HJ] 3elll1HCKOrO PAH r MOCKBa B MCTOpM'eCKOM nocneaobatenbhoctm M3nOJKeHb 3Tanbl pa3bmtmj M HaM60nee 3Ha'4MMble AOCTMJKeHMJ ~HCTMTYTa oprahm'leckom XMMMM (~OX) B 06naCTM KaTanM3a B nepbyo O'lepeAb OpraHM'eCKOrO OCHOBOnOnOJKHMKOM KoToporo B CCCP 6b1n HA 3enMHcKMH c03aabw\1~ HaY'4HYO wkony onpeaen\1bwylo B nocneayoujem BKnaA ero Y\feH\1KOB BCeM\1pHO \13BeCTHbX Y\feHblx B cjjyhaameh TanbHYO HaYKY 0 KaTan\13e CO3AaH\1e HOBblX KaTan\1T\1'1eCK\1X npoljeccob M npomblwnehhblx KaTan\13aTopoB np\1bepehbl np\1mepbl BHeApeHMJ HaY\fHblx pa3pa60tok ~OX B npom3boactbo C03AaHMe KaTanM3aTopoB B MHCTMTYTe 6a3MpoBanocb Ha WMpOKOM Mcnonb 30BaHMM cjjm3mkoxmmm'4eckmx MeToAoB M HaY\fHblx noaxoaob K TeXHonorMM KaTanM3aTopoB noka3aho 3cpcpeKTMBHOe COTPYAHM'eCTBo Y\feHblx ~OX co cneljmanmctamm npmknaahoro KaTanM3a M npomblwnehhoctm o6ecne'lmbwee ycnewhoe BHeApeHMe B npom3boactbo pe3ynbtatob HaY\fHblx MCC11eAoBaHMH MHOrMe M3 3TMX TpaAMLjMM coxpahjlotcs AO HaCTOJl~erO BpeMeHM Ha CTpaHMLjaX >KypHana npeactabneha B Ka'leCTBe npmmepa nmwb He60nbWaJl 'actb pe3ynbtatob M AOCTMJKeHMM ~OX B 06naCTM KaTanM3a noap06hoe M3 nojkehme 6YAeT ony6nmkobaho n03jke B KaTanMTM'eCKOM 6lOnneTeHe The stages of development are set forth n a hstorcal progresson ncludng the most mportant achevements of the nsttute of Organc Chemstry (OC) n the feld of catalyss frst of all organc catalyss the founder of whch n the USSR was ND Zelnsky who establshed the scentfc school that determned n succeedng years the contrbuton of hs dscples worldfamous scentsts n the fundamental scence on catalysts creaton of new catalytc processes and ndustra! catalysts Examples of applcaton of the OC sc entfc developments n the producton are gven Creaton of catalysts n the nsttute was based on a broad applcaton of physcalchemcal methods and scentfc approaches to the catalyst technology Effcent cooperaton of the scentsts of OC wth specalsts of! appled catalyss and ndustry provdng successful applcaton of the results scentfc nvestgatons n the producton process s shown 11 j Many of these tradtons reman tll now: The extent of t~e journalgves just ~ lttle porton ~f the r~sults and achevements of OC n the feld of catalyss as an example A detaled statement wll be publshed later n the Catalytc Bulletn 55